Characterization of bentonite, vermiculite and soil as potential materials to compose the natural barriers in a near-surface repository

Autores/as

  • Daisy Mary Marchezini dos Santos Centro de Desenvolvimento da Tecnologia Nuclear image/svg+xml
  • Samara Alves Barroso ,
  • Thaís Braga Teixeira ,
  • Clédola Cássia Oliveira de Tello ,

DOI:

https://doi.org/10.15392/2319-0612.2022.1950

Palabras clave:

bentonite, soil, expanded vermiculite, repository, radioactive waste

Resumen

The use of nuclear technology is growing in Brazil, where it is possible to carry out the entire nuclear fuel cycle. This technology generates radioactive waste that must be treated before being released into the environment or stored in suitable facilities. Then, the first national repository - CENTENA - will be implemented, where all low and intermediate level radioactive waste generated in Brazilian territory will be safely stored. One of the barriers that will compose the repository will be composed of natural materials such as soils and clays, the latter for having a high adsorption and cation exchange capacities and swelling potential. The purpose of the article is to show the research carried out in Centro de Desenvolvimento da Tecnologia Nuclear (CDTN) with natural materials aiming their use in natural barriers. Four materials were characterized: CDTN soil, this soil with bentonite, expanded vermiculite and bentonite, using the clay characterization protocol. Primary mineralogical, physical and chemical analyzes were performed, such as X-ray diffraction, scanning electron microscopy, particle size distribution, specific surface area and cation exchange capacity. The results showed that these clays are potentially candidates for composing CENTENA's natural barriers.

Descargas

Los datos de descarga aún no están disponibles.

Biografía del autor/a

  • Daisy Mary Marchezini dos Santos, Centro de Desenvolvimento da Tecnologia Nuclear
    Daisy Marchezini é aluna de Doutorado em Ciência e Tecnologia das Radiações, Minerais e Materiais do Programa de Pós-Graduação do Centro de Desenvolvimento da Tecnologia Nuclear desde 2017. Ela recebeu seu mestrado em 2017 pela mesma instituição. Seus interesses de pesquisa incluem rejeitos radioativos e seus depósitos. Atualmente faz parte do quadro de colaboradores do setor SEGRE/CDTN.

Referencias

Ministério de Minas e Energia – MME (2018) – Plano Nacional de Energia - PNE 2050: Potencial dos Recursos Energéticos no Horizonte 2050. Rio de Janeiro, Brazil. 2018. Available at: <https://www.epe.gov.br >. Last accessed: 30 Jan. 2022

CNEN – Comissão Nacional de Energia Nuclear. Gerência de Rejeitos Radioativos de baixo e médio níveis de radiação. CNEN-NN-8.01, Rio de Janeiro: CNEN, 2014. 45p.

CNEN – Comissão Nacional de Energia Nuclear. Licenciamento de depósitos de rejeitos radioativos de baixo e médio níveis de radiação. CNEN-NN-8.02, Rio de Janeiro: CNEN, 2014. 32p.

IAEA – International Atomic Energy Agency. Selection of technical solutions for the management of radioactive waste. TECDOC-1817, Vienna: IAEA, 2017. 114p.

SANTOS, D. M. M., TELLO, C. C. O. Protocol for characterization of clay as a backfill and coverage layers for near surface repository. Brazilian Journal of Radiation Sciences, v. 7 (2A), 14p, 2019.

TEIXEIRA, T. B., TELLO, C. C. O. Characterization of expanded vermiculite to use as natural barrier in repository. Brazilian Journal of Radiation Sciences, v. 9 (1A), 11p, 2021.

BARROSO, S. A., TELLO, C. C. O. Study of a mixture of soil and brazilian bentonite using a protocol for clay characterization for near-surface radioactive waste repository. Brazilian Journal of Radiation Sciences, v. 9 (1A), 13p, 2021.

ROSÁRIO, J. A., MIGUEL, R. F., ROSÁRIO, D. A., KUHNEN, N. C., RIELLA, H. G. Factorial design applied to sodium activation of a Brazilian bentonite. Cerâmica, v. 65, p. 185-189, 2019.

CINTRA, C. L. D., PAIVA, A. E. M., BALDO, J. B. Masonry mortars containing expanded vermiculite and rubber aggregates from recycled tires - Relevant properties. Cerâmica, v. 60, p. 69-76, 2014.

ALBERS, A. P. F., MELCHIADES, F. G., MACHADO, R., BALDO, J. B., BOSCHI, A. O. A simple method for the characterization of clay minerals by X-ray diffraction. Cerâmica, v. 48, p. 34-37, 2002.

ABNT – Associação Brasileira de Normas Técnicas. Soil: Grain size analysis. NBR 7181, Rio de Janeiro: ABNT, 2016. 12p.

GREGG, S., SING, K. S. W. Adsorption, Surface Area and Porosity, 2nd ed. London: Academic Press, 1982.

CDTN – Centro de Desenvolvimento da Tecnologia Nuclear. Determinação da capacidade de troca catiônica (CTC) de argilas utilizando o método da adsorção de adsorção de azul de metileno (AAM). INTERNAL NOTE, Belo Horizonte: CDTN, 2012. 9p.

MCBRIDE, M. B. Environmental chemistry of soils, 1st ed. New York: Oxford University Press, 1994.

BRADY, N. C., WEIL, R. R. Elementos da natureza e propriedades dos solos, 3rd ed. Porto Alegre: Bookman, 2012.

ACEVEDO, N. I. A., ROCHA, M. C. G., BERTOLINO, L. C. Mineralogical characterization of natural clays from Brazilian Southeast region for industrial applications. Cerâmica, v. 63, p. 253-262, 2017.

LUZ, A. B., LINS, F. A. Rochas & minerais Industriais: usos e especificações, 2nd ed. Rio de Janeiro: CETEM/MCT, 2008.

AGUIAR, M. R. M. P., NOVAES, A. C., GUARINO, A. W. S. Removal of heavy metals from wastewaters by aluminosilicate. Química Nova, v. 25, p. 1145-1154, 2002.

SUZUKI, S., SAZARASHI, M., AKIMOTO, T., HAGINUMA, M., SUZUKI, K. A study of the mineralogical alteration of bentonite in saline water. Applied Clay Science, v. 41, p. 190-198, 2008.

Descargas

Publicado

2022-12-04

Número

Sección

INAC 2021_XV ENAN

Cómo citar

Characterization of bentonite, vermiculite and soil as potential materials to compose the natural barriers in a near-surface repository. Brazilian Journal of Radiation Sciences (BJRS), Rio de Janeiro, Brazil, v. 10, n. 3B (Suppl.), 2022. DOI: 10.15392/2319-0612.2022.1950. Disponível em: https://bjrs.org.br/revista/index.php/REVISTA/article/view/1950. Acesso em: 17 jul. 2025.