Instrumental Neutron Activation Analysis (INAA) As-sessment of REE of Soil from Mining Site Umuahia, Abia State, South East, Nigeria

M. E. Onudibia; P. S. C. Silva; A.A. Essiett; G. S. Zahn; F. A. Genezini; H. M. S. M. D Linhares; N. C. Nnamani; M. C. Bede; F. O. Okoh; E. E. Imeh; C. M. Odoh

doi:10.15392/2319-0612.2024.2336

Autores

M. E. Onudibia Federal University Wukari / IPEN / CRPq , ,
P. S. C. Silva IPEN / CRPq / USP , IPEN / CRPq / USP , IPEN / CRPq / USP
A.A. Essiett University of Uyo, Nigeria , ,
G. S. Zahn IPEN / CRPq / USP , ,
F. A. Genezini IPEN / CRPq / USP , ,
H. M. S. M. D Linhares IPEN / CRPq / USP , ,
N. C. Nnamani Ahmadu Bello University, Nigeria , ,
M. C. Bede
F. O. Okoh Federal University Wukari, Nigeria , ,
E. E. Imeh University of Uyo, Nigeria , ,
C. M. Odoh Federal University Wukari, Nigeria , ,

DOI:

https://doi.org/10.15392/2319-0612.2024.2336

Palavras-chave:

elementos de terras raras, solo de mineração de argila, Umuahia, Nigéria, geoacumulação

Resumo

Neste trabalho, o objetivo principal foi examinar a concentração e o padrão de distribuição de elementos terras raras (ETR) no solo de Umuahia, Estado de Abia, do Sudeste da Nigéria, num local de mineração de argila em comparação com um local não contaminado a aproximadamente 3 km de distância. Os ETR foram determinados por Análise por ativação neutrônica instrumental (INAA) no IPEN, Brasil. A mineralogia principal das amostras foi determinada por difração de raios-X. Foram determinados os seguintes ETR: Ce, Eu, La, Lu, Nd, Sm, Tb e Yb. As amostras de solo da área de mineração apresentam quartzo e caulinita como principais constituintes, com concentrações de ETR comparáveis às da crosta continental superior e do composto de xisto norte-americano. O índice de geoacumulação calculado (IGeo) indica que os ETR têm origem natural e a relação ∑LETR/∑PETR mostra um enriquecimento dos ETR leves em relação aos pesados, em amostras da área de mineração de argila.

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