Sustainable synthesis of cobalt nanoparticles for supercapacitor application
DOI:
https://doi.org/10.15392/2319-0612.2024.2624Palabras clave:
sustainable, synthesis, radiation, supercapacitorsResumen
The growing demand for renewable energy sources and the continuous increase in global energy demand are responsible for the need to develop new forms of energy storage. In this context, supercapacitors emerged due to properties, such as high charge density, long durability and reduced environmental impact. This work aims to develop electrodes based on cobalt oxide synthesized by ionizing radiation for use in supercapacitors. Synthesis by ionizing radiation consists of a sustainable and ecological approach to the production of nanoparticles, reducing the need for toxic reagents and high temperatures. Cobalt oxide nanoparticles were synthesized by irradiating a solution of cobalt acetate, followed by vacuum filtration and drying. The electrochemical properties of the material were evaluated using cyclic voltammetry in 1 M KOH. The results indicated that the cobalt oxide electrodes have a significant energy storage capacity, indicating their potential for use in supercapacitors.
Descargas
Referencias
[1] ELALFY, D. A.; GOUDA, E.; KOTB, M. F.; BUERES, V. D. ; BURES, V., SEDHOM, B. E. Comprehensive review of energy storage systems technologies, objectives, challenges, and future trends. Energy Strategy Reviews, Netherlands, v. 54, 101482, 2024.
[2] DISSANAYAKE, K.; KULARATNA-ABEYWARDANA, D. A review of supercapacitors: Materials, technology, challenges and renewable energy applications. Journal of Energy Storage, Netherlands, v. 96, 112563, 2024.
[3] YAN, J.; WEI, T.; QIAO, W.; SHAO, B.; ZHAO, Q.; ZHANG, L.; FAN, Z. Rapid microwave-assisted synthesis of graphene nanosheet/Co3O4 composite for supercapacitors. Electrochimica Acta, Netherlands, v. 55, 6973–6978, 2010.
[4] ALY, S.T.; SAED, A.; MAHMOUD, A.; BADR, M.; GARAS, S. S.; YAHYA, S.; HAMAD, K. H. Preparation of magnetite nanoparticles and their application in the removal of methylene blue dye from wastewater. Scientific Reports, v. 14, 20100, 2024.
[5] BABU, C.R.; AVANI, A.V.; SHAJI S.; ANILA, E. I. Electrochemical characteristics of Co3O4 nanoparticles synthesized via the hydrothermal approach for supercapacitor applications. Journal of Solid State Electrochemistry, United Kingdom, v. 28, 2203–2210 2024.
[6] SAIDIN, N. U.; CHOO, T. F.; YUNUS, R. M.; ZALI, N. M.; KOK, K. Y. Kok, WONG, W. Y.; LIM, K. L. One-pot gamma radiolysis synthesis of a graphene oxide-supported cobalt oxyhydroxide electrocatalyst for oxygen reduction reaction, Radiation Physics and Chemistry, Netherlands, v. 205, 110680, 2023.
[7] ALREHAILY, L. M., JOSEPH, J. M.; BIESINEGR, M. C.; GUZONAS, D. A.; WREN, J. C. Gamma-radiolysis-assisted cobalt oxide nanoparticle formation Physical Chemistry Chemical Physics, International, v.15, p. 1014-1024, 2013.
[8] DOBELIN, N.; KLEEBERG, R. Profex; a graphical user interface for the Rietveld refinement program BGMN. Journal of Applied Crystallography, United Kingdom, v. 48, 1573-1580, 2015.
[9] RABANI, I.; YOO, J.; KIM, H.; LAM, D. V.; HUSSAIN, S.; KARUPPASAMY, K. SEO Y. Highly dispersive Co3O4 nanoparticles incorpor ated into a cellulose nanofiber for a high-performance flexible supercapacitor, Symmetric supercapacitor based on Co3O4 nanoparticles with an improved specific capacitance and energy density.
Nanoscale, v. 13, 355-370, 2020.
[10] DE FARIA JUNIOR, R. N.; CASINI, J. C. S. ; FERNANDEZ, A. P. R. Supercapacitor : conceitos básicos, materiais e métodos. São Paulo, SP, BR : Ed. dos Autores, 2021.
Descargas
Publicado
Número
Sección
Categorías
Licencia
Derechos de autor 2024 Miguel Duarte, Thye Foo Choo, Karina de Oliveira Gonçalves, Daniel Vieira da Silva, Rubens Nunes de Faria Junior, Solange Kazumi Sakata
Esta obra está bajo una licencia internacional Creative Commons Atribución 4.0.
Licencia: los artículos de BJRS tienen una licencia internacional Creative Commons Attribution 4.0, que permite el uso, el intercambio, la adaptación, la distribución y la reproducción en cualquier medio o formato, siempre que se otorgue el crédito correspondiente al autor o autores originales y a la fuente, proporcione un enlace a la licencia Creative Commons e indique si se realizaron cambios. Las imágenes u otros materiales de terceros en el artículo están incluidos en la licencia Creative Commons del artículo, a menos que se indique lo contrario en una línea de crédito al material. Si el material no está incluido en la licencia Creative Commons del artículo y su uso previsto no está permitido por la regulación legal o excede el uso permitido, el autor deberá obtener el permiso directamente del titular de los derechos de autor. Para ver una copia de esta licencia, visite http://creativecommons.org/licenses/by/4.0/
