The characterization of naturally occurring radionuclides in concrete incorporating fly ash as partial cement replacement

Authors

  • Mevlan Qafleshi Polytechnic University of Tirana, Faculty of Mathematical Engineering and Physical Engineering, Tirana, Albania
  • Misin Misini University of Prishtina “Hasan Prishtina”, Faculty of civil engineering and architecture, Prishtina, Kosovo
  • Driton Kryeziu Polytechnic University of Tirana, Tirana, Albania
  • Lulezime Aliko Polytechnic University of Tirana, Tirana, Albania

DOI:

https://doi.org/10.15392/bjrs.v6i1.193

Keywords:

Exposure, Concrete, Fly Ash, NORMs, HPGe Gamma Ray Spectrometry, Radiation Doses, Kosovo

Abstract

Kosovo thermal power plants (TPP) produce annually more than 1 million tons of fly ash as a byproduct of lignite combustion. The focus of this study was to characterize the activity concentration of natural radionuclides of hardened concrete specimens with Hyper Pure Germanium gamma-ray spectrometry (HPGe). Concrete mixtures with different content of fly ash as cement replacement were prepared.    Four concrete mixes with 15, 20, 25 and 30% fly ash replacing the respective content of cement were tested for activity concentration of 40K, 226Ra and 232Th, activity concentration index, indoor and outdoor specific and annual absorption dose rates. Two other reference mixes were normal concrete with cement. The obtained results were compared to reference concrete mixtures without fly ash.  The results of measurements in six concrete mixtures showed that the activity concentrations of 40K, 226Ra and 232Th were very low in all concrete specimens. 

Downloads

Download data is not yet available.

References

ICMM (Independent Commission for Mines and Minerals). Mineral Deposits, Lignite, R. of Kosovo. Prishtina, Kosovo, 2015.

MED (Ministry of Economic Development, Republic of Kosovo). Annual Energy balance of R. of Kosovo for the year 2013, Prishtina, Kosovo, 2013.

ASK (Kosovo Agency of Statistics). Kosovo Population and Housing, Census 2011, 2015.

KEC (Kosovo Energy Corporation J.S.C.). Generation Division, 2015.

UNMIK (United Nations Interim Administration Mission in Kosovo) EU Pillar, PISG, Energy Office. Energy Strategy and Policy of Kosovo. Kosovo, 2005.

WBSD (World Business Council for Sustainable Development). Cement Technology Roadmap 2009. World Business Council for Sustainable Development. P.2 (2009); UNEP. Greeing Cement Production. Unites Nations Environment Programme, 2010.

USGS (United States Geological Survey). Mineral Commodity Summaries 2014. USA, 2014.

BANERJEE, R.; Y. CONG, D. GIELEN; G. JANNUZZI; F. MARÉCHAL; A. T. MCKANE; M. A. ROSEN; D. VAN ES; E. WORRELL. Chapter 8 - Energy End Use: Industry. In Global Energy Assessment - Toward a Sustainable Future, Cambridge University Press, Cambridge, UK and New York, NY, USA and the International Institute for Applied Systems Analysis, Laxenburg, Austria, 2012, p. 513-574.

IPCC (Intergovernmental Panel on Climate Change). Climate Change Mitigation. Contribution of Working Group III to the fourth Assessment Report. Section 7.4.5.1: Minerals-Cement. Geneva, Switzerland, 2007.

CEN (European Committee for Standardization). EN 450-1: 2012. Fly ash for concrete, Part 1: Definition, specifications and conformity criteria. Brussels, 2012.

ASTM International (American Society for Testing and Materials). ASTM C618 12a, Standard Specification for Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use in Concrete. Book of Standards, Volume: 04.02-Concrete and Aggregates, 2012, 3pp

KOVLER, K. Radiological constraints of using building materials and industrial by-products in construction. Construct. Build. Mater, v. 23, p.246–253, 2009.

World Nuclear Association. Naturally Occurring Radioactive Materials-NORM. London, UK, 2015.

HASANI, F.; SHALA, F.; XHIXHA, G.; HODOLLI, G.; KADIRI, S.; BYLYKU, E.; CAFRKU, E. Naturally occurring radioactive materials (NORMS) generated from lignite-fired power plants in Kosovo. Journal of Environmental Radioactivity, v. 138, p.156-161, 2014.

XHIXHA, G.; BEZZON, G.P.; BROGGINI, C.; BUSO, G.P.; CACIOLLI, A.; CALLEGARI, I.; DE BIANCHI, S.; FIORENTINI, G.; GUASTALDI, E.; MANTOVANI, F.; MASSA, G.; MENEGAZZO, R.; MOU, L.; PASQUINI, A.; ALVAREZ, R; SHYTI, C; XHIXHA, M; The worldwide NORM production and a fully automated gamma-ray spectrometer for their characterization. J. Radioanal. Nucl. Chem, v. 295, p. 445-457, 2013.

MALHOTRA, V. M. Reducing CO2 emission – The role of fly ash and other supplementary cementitious materials. Concrete International, p. 42-45, 2006.

MEHTA, P. K. Global concrete industry sustainability – Tools for moving toward to cut carbon emission. Concrete International. p. 45-48, 2009.

QAFLESHI, M.; KRYEZIU, R.D.; ALIKO, L. Particulate and gaseous pollutants as byproducts from the combustion process in lignite fired power plants. Case: Kosova A and Kosova B thermal power plants. The 2nd International Conference on Research and Education – “Challenges Toward the Future” (ICRAE2014), ICRAE2014 Conference- Paper Proceedings, ISSN: 2308-0825, Shkoder, Albania, 2014.

CEN (European Committee for Standardization). EN 197-1, 2000. Cement-part 1: Composition, Specification and Conformity Criteria for Common Cements., Brussels, Belgium, 2000.

Headwaters Resources. Fly Ash for Concrete. Utah, USA, 2013.

Antiohos, S.; Tsimas, K.T. Reactive silica of fly ash as an indicator for the mechanical performance of blended cements. National Technical University of Athens, Athínai, Attica, Greece, 2006. DOI: 10.1007/978-1-4020-5104-3-49.

ASTM International (American Society for Testing and Materials). Annual Book of ASTM Standards, ASTM International, West Conshohocken, PA, USA (2007).

CEN (European Committee for Standardization). EN 206-1 Concrete – Part 1: Specification, performance, production and conformity. Brussels, 2000.

ADROVIĆ, F.D.; TODOROVIĆ, D.; NINKOVIĆ, M.M; PROKIĆ, M. Investigation of the contents of natural radionuclides in coal and ashes from Kosovian power plants. In: Proceedings of the IRPA Regional Symposium on Radiation Protection, Prague, 1997, p334-336.

CEN (European Committee for Standardization). EN 12620 Aggregates for concrete, 2013.

CEN (European Committee for Standardization). EN 934-2:2009, Admixtures for concrete, mortar and grout - Part 2: Concrete admixtures - Definitions, requirements, conformity, marking and labeling, 2009.

EC (European Commission) radiological protection principles concerning the natural radioactivity of building materials, European Commission. Radiation Protection 112. Directorate-General Environment, Nuclear Safety and Civil Protection, 1999

KARANGELOS, D.J.; PETROPOULOS, N.P; ANAGNOSTAKIS, M.J; HINIS, E.P.; SIMOPOULOS, S.E. Radiological characteristics and investigation of the radioactive equilibrium in the ashes produced in lignite-fired power plants. Journal of Environmental Radioactivity. v.77, p. 233–246, 2004. doi:10.1016/j.jenvrad.2004.03.009.

NUCCETELLI, C.; RISICA, R.; D’ALESSANDRO, M.; TREVISI, R. Natural radioactivity in the European Union: Robustness of the activity concentration index I and comparison with a room model. Journal of radiological protection, v. 32, p. 349-258 2012. Doi:10.1088/0952-4746/32/3/349.

MARKKANEN, M. Radiation Dose Assessments for Materials with Elevated Natural Radioactivity. Report STUK-B-STO 32, Finish Centre for Radiation and Nuclear Safety. Helsinki, 25 p. + app. 13 p, 1995.

UNSCEAR (United Nations Scientific Committee on the Effects of Atomic Radiation). Exposures from Natural Radiation Sources. United Nations, 2008.

SHARMA, P.; MEHE, K.P.; MISHRA, P. K. Terrestrial gamma radiation dose measurement and health hazard along river Alaknanda and Ganges in India. Journal of Radiation Research and Applied Sciences, v.7, p.595 -600, 2014.

XHIXHA, G.; AHMETI, A.; BEZZON, G.P.; BITRI, M.; BROGGINI, C.; BUSO, P.G.; CACIOLLI, A.; CALLEGARI, I.; CFARKU, F.; COLONNA, T.; FIORENTINI, G.; GUASTALDI, E.; MANTOVANI , F.; MASSA, G.; MENEGAZZO, R.; MOU, L.; PRIFTI, D.; ALVAREZ, C.R.; KUQI, S. DH.; SHYTI, M.; TUSHE, L.; KAÇELI, M.XH. First characterisation of natural radioactivity in building materials manufactured in Albania. Radiation Protection Dosimetry. v.155, No.2, p.217-223, 2013.

UNSCEAR (United Nations Scientific Committee on the Effects of Atomic Radiation). Report to the General Assembly. Annex B: Exposures from Natural Radiation Sources, United Nations Scientific Committee on the Effects of Atomic Radiation, ISBN-10: 9211422388, NY, 2000.

UNSCEAR (United Nations Scientific Committee on the Effects of Atomic Radiation). Report to the General Assembly, v. 1, Annex. B; United Nations, 2008.

Downloads

Published

2018-01-28

How to Cite

Qafleshi, M., Misini, M., Kryeziu, D., & Aliko, L. (2018). The characterization of naturally occurring radionuclides in concrete incorporating fly ash as partial cement replacement. Brazilian Journal of Radiation Sciences, 6(1). https://doi.org/10.15392/bjrs.v6i1.193

Issue

Section

Articles