New article published in 12(4A) - ENAN / INAC 2024

Byproduct-based zeolite type A as absorbent material for decontamination of simulated radioactive wastewater

Abstract: The secure disposal of radioactive wastewater, a waste from nuclear operations, presents a significant challenge due to the presence of hazardous radionuclides like cesium. The efficient removal of cesium, a major fission product with a long half-life and potent radiation, is crucial for environmental and human health protection. Zeolites, with their high ion exchange capacity and porous structure, offer a promising solution for cesium removal from wastewater. The potential to synthesize zeolites from abundant and cost-effective agro-industrial residues further enhances their appeal for sustainable wastewater treatment. The present study investigates the adsorption of cesium from simulated radioactive wastewater using zeolite type A synthesized from sugarcane bagasse ash, a readily available Brazilian byproduct. The synthesized zeolite was characterized by X-ray fluorescence spectroscopy, X-ray diffraction, and thermal analysis techniques. The results confirmed the successful synthesis of high-purity zeolite A with excellent adsorption capacity for cesium. The structural integrity and thermal stability of the zeolite were maintained even after cesium adsorption, making it suitable for immobilization processes. The findings highlight the potential of zeolite synthesized from sugarcane bagasse ash as an effective and sustainable material for the treatment and removal of cesium from radioactive wastewater, contributing to environmental remediation efforts in the nuclear industry. Read full article

APPLICATION OF IONIZING RADIATION IN THE PRESERVATION AND CONSERVATION OF TAXIDERMIED ANIMAL SKINS IN NATURAL HISTORY MUSEUMS

Abstract: The great interest in the development of research involving ionizing radiation aims to significantly increase the conservation of the skins of taxidermized animals, both for scientific collections and on display, causing their infection and disinfestation, without altering their originality, reducing the use of chemical products, presenting a safe and efficient technology. The preservation of taxidermied mammals has been widely used for educational, scientific and Museum display purposes. However, prolonged exposure to environmental factors or the excessive use of chemicals to store these materials in the collection can affect the integrity of the skin of these animals. In this study, we investigated the effects of gamma radiation on the structure and composition of the skin of taxidermied mammals, with the aim of contributing to a better understanding of conservation processes and the potential risks they may entail. Taxidermy is an animal preservation technique that has been used for centuries, allowing specimens to be arranged in their natural form and/or preserved for scientific studies. Samples of skin from animals from the Brazilian flora were selected, deer, coati, prawn and bison, and these samples were irradiated at doses of 1, 3, 5, 10 and 15 kGy. After gamma irradiation, they were characterized by colorimetry, scanning electron microscopy (SEM), optical microscopy (OM), infrared microscopy (FTIR) and mechanical analysis. The results show that the doses of gamma irradiation that the samples were subjected to did not compromise their physical and chemical integrity. This indicates the possibility of using gamma radiation for disinfestation and disinfection. Read full article