Byproduct-based zeolite type A as absorbent material for decontamination of simulated radioactive wastewater
DOI:
https://doi.org/10.15392/2319-0612.2024.2650Keywords:
Radioactive Wastewater, Cesium removal, Zeolite, Sugarcane bagasse ashAbstract
The secure disposal of radioactive wastewater, a waste from nuclear operations, presents a significant challenge due to the presence of hazardous radionuclides like cesium. The efficient removal of cesium, a major fission product with a long half-life and potent radiation, is crucial for environmental and human health protection. Zeolites, with their high ion exchange capacity and porous structure, offer a promising solution for cesium removal from wastewater. The potential to synthesize zeolites from abundant and cost-effective agro-industrial residues further enhances their appeal for sustainable wastewater treatment. The present study investigates the adsorption of cesium from simulated radioactive wastewater using zeolite type A synthesized from sugarcane bagasse ash, a readily available Brazilian byproduct. The synthesized zeolite was characterized by X-ray fluorescence spectroscopy, X-ray diffraction, and thermal analysis techniques. The results confirmed the successful synthesis of high-purity zeolite A with excellent adsorption capacity for cesium. The structural integrity and thermal stability of the zeolite were maintained even after cesium adsorption, making it suitable for immobilization processes. The findings highlight the potential of zeolite synthesized from sugarcane bagasse ash as an effective and sustainable material for the treatment and removal of cesium from radioactive wastewater, contributing to environmental remediation efforts in the nuclear industry.
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[1] ZHUANG, Shuting and WANG, Jianlong. Cesium removal from radioactive wastewater by adsorption and membrane technology. Frontiers of Environmental Science & Engineering. v. 18, n. 3, p. 38. 2024. DOI 10.1007/s11783-024-1798-1. Available from: https://link.springer.com/10.1007/s11783-024-1798-1. DOI: https://doi.org/10.1007/s11783-024-1798-1
[2] LALHMUNSIAMA, KIM, Jae Gyu, CHOI, Suk Soon and LEE, Seung Mok. Recent Advances in Adsorption Removal of Cesium from Aquatic Environment. Applied Chemistry for Engineering. v. 29, n. 2, p. 127–137. 2018. DOI 10.14478/ACE.2018.1019. Available from: https://doi.org/10.14478/ace.2018.1019.
[3] KWON, Sunki, LIM, Jongmyoung, SEOUNG, Donghoon, CHO, Youngjin and PARK, Byungkyu. Comparative study of the cesium adsorption behavior of montmorillonite and illite based on their mineralogical properties and interlayer cations. Journal of Hazardous Materials Advances. v. 10, p. 100258. 2023. DOI 10.1016/J.HAZADV.2023.100258. DOI: https://doi.org/10.1016/j.hazadv.2023.100258
[4] DE CARVALHO IZIDORO, Juliana, FUNGARO, Denise Alves and CATALDO, Eleonora. Zeolites synthesized from agro‐industrial residues applied in agriculture: A review and future prospects. Soil Use and Management. v. 40, n. 1, p. e13003. 2024. DOI 10.1111/sum.13003. DOI: https://doi.org/10.1111/sum.13003
[5] IZIDORO, Juliana de C., FUNGARO, Denise A., ABBOTT, Jennifer E. and WANG, Shaobin. Synthesis of zeolites X and A from fly ashes for cadmium and zinc removal from aqueous solutions in single and binary ion systems. Fuel. v. 103, p. 827–834. 2013. DOI 10.1016/j.fuel.2012.07.060. DOI: https://doi.org/10.1016/j.fuel.2012.07.060
[6] IZIDORO, Juliana de C., FUNGARO, Denise Alves, DOS SANTOS, Fernando S. and WANG, Shaobin. Characteristics of Brazilian coal fly ashes and their synthesized zeolites. Fuel Processing Technology. v. 97, p. 38–44. 2012. DOI 10.1016/j.fuproc.2012.01.009. DOI: https://doi.org/10.1016/j.fuproc.2012.01.009
[7] TIAN, Quanzhi and SASAKI, Keiko. Application of fly ash-based materials for stabilization/solidification of cesium and strontium. Environmental Science and Pollution Research. v. 26, n. 23, p. 23542–23554. 2019. DOI 10.1007/S11356-019-05612-1/METRICS. DOI: https://doi.org/10.1007/s11356-019-05612-1
[8] PATEL, Himanshu. Environmental valorisation of bagasse fly ash: a review. RSC Advances. v. 10, n. 52, p. 31611–31621. 2020. DOI 10.1039/D0RA06422J. DOI: https://doi.org/10.1039/D0RA06422J
[9] MAHIMA KUMAR, M., IRSHAD, K. A. and JENA, Hrudananda. Removal of Cs+ and Sr2+ ions from simulated radioactive waste solutions using Zeolite-A synthesized from kaolin and their structural stability at high pressures. Microporous and Mesoporous Materials. v. 312, p. 110773. 2021. DOI 10.1016/J.MICROMESO.2020.110773. DOI: https://doi.org/10.1016/j.micromeso.2020.110773
[10] KIM, YANG, SUBRAMANIAN, V., FIROR, ROGER L. and SEFF, KARL. Four Crystal Structures of BaxNa12-2x-A (1≤x≤6) Relating to the Instability of Barium-Exchanged Zeolite A Toward Dehydration. In : Adsorption and Ion Exchange with Synthetic Zeolites. 1980. p. 137–153. DOI: https://doi.org/10.1021/bk-1980-0135.ch007
[11] GREAVES, G.N. Zeolite Instability and Collapse. In : Phase Transitions and Self-Organization in Electronic and Molecular Networks. Kluwer Academic Publishers : Boston, [no date]. p. 225–246. DOI: https://doi.org/10.1007/0-306-47113-2_15
[12] OMERAŠEVIĆ, Mia, LUKIĆ, Miodrag, SAVIĆ-BISERČIĆ, Marjetka, SAVIĆ, Andrija, MATOVIĆ, Ljiljana, BAŠČAREVIĆ, Zvezdana and BUČEVAC, Dušan. Permanent disposal of Cs ions in the form of dense pollucite ceramics having low thermal expansion coefficient. Nuclear Engineering and Technology. v. 52, n. 1, p. 115–122. 2020. DOI 10.1016/J.NET.2019.07.001. DOI: https://doi.org/10.1016/j.net.2019.07.001
[13] MIMURA, Hitoshi and KANNO, Takuji. Distribution and fixation of cesium and strontium in zeolite a and chabazite. Journal of Nuclear Science and Technology. v. 22, n. 4, p. 284–291. 1985. DOI 10.1080/18811248.1985.9735658. Available from: https://www.tandfonline.com/action/journalInformation?journalCode=tnst20. DOI: https://doi.org/10.1080/18811248.1985.9735658
[14] KRÓL, Magdalena Katarzyna and JELEŃ, Piotr. The Effect of Heat Treatment on the Structure of Zeolite A. Materials. v. 14, n. 16, p. 4642. 2021. DOI 10.3390/ma14164642. DOI: https://doi.org/10.3390/ma14164642
[15] ALTOMARE, Angela, CORRIERO, Nicola, CUOCCI, Corrado, FALCICCHIO, Aurelia, MOLITERNI, Anna and RIZZI, Rosanna. QUALX2.0 : a qualitative phase analysis software using the freely available database POW_COD. Journal of Applied Crystallography. v. 48, n. 2, p. 598–603. 2015. DOI 10.1107/S1600576715002319. DOI: https://doi.org/10.1107/S1600576715002319
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