Brazilian clays for environmental solutions applied to radioactive waste management

Authors

  • Gabriel Gonzalo Machado Entrepreneurship project leader at Argilos
  • Victoria Krupskaya Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry Russian Academy of Science (IGEM RAS)
  • Sergey V Zakusin Russian Academy of Sciences, Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry Staromonetny Pereulok, 35 – 119017 Moscow, Russia
  • Julio HARADA ARGILOS
  • Rodrigo Papai de Souza IPT
  • Leandro Goulart Araujo IPEN/CNEN
  • Denise Crocce Espinosa USP
  • Edy L.T. Montalvan USP
  • Henrique Kahn USP
  • Roberto Vicente IPEN/CNEN
  • Sabine Guilhen IPEN/CNEN

DOI:

https://doi.org/10.15392/bjrs.v9i1A.1539

Keywords:

CLAYS, SMECTITE, TENORM, CESIUM, ADSORPTION, EBS

Abstract

Clays have been adopted in most nuclear waste producing countries as a key constituent in engineered barrier systems for final disposal facilities at all levels of radioactive wastes (LILW-SL, LILW-LL, and HLW). The following study presents a thorough characterization upon five Brazilian clay-rich deposits, mostly smectite bearing clays, aiming to evaluate their expected performance as barrier under the conditions associated to a Low and Intermediate Level Waste Repository; being the former a matter of national strategic interest. Samples coming from the Brazilian states of Paraná, Bahia, Paraíba, and Maranhão were treated and analyzed by means of X-Ray diffraction as main technique, and complemented by FTIR, LALLS, XRF, and SEM-EDS, in order to establish the mineralogical composition, particle size distribution, and chemical composition. Moreover, several standard clay treatments over the <1 μm size fraction were carried out to reveal information regarding layer charge, major interlayer cations, unit formula and other crystal features of smectite species present in a mineralogical assembly, aiming to provide information for the construction of a molecular model over which would be realistic to simulate the diffusion of radionuclides. Results obtained on 133Cs adsorption experiments indicate that mineralogical composition would probably be the single most influential factor controlling transport capacity of positively charged radionuclides in the current setup. The composition is especially expressed in terms of smectite contents, favoring montmorillonite rich materials containing majorly Na+ as compensating cation in interlayer position. All tested samples can be considered as suitable candidates to be used in the design of final destination storage for nuclear waste. Thus, efficiency on 133Cs adsorption trials also indicate that these materials could have potential uses as sorptive matrices (Sorbents) for water treatment of radionuclide polluted waters such as TENORM waste waters. However, these trends are yet to be contrasted against hydraulic conductivity measurements and swelling pressure in order to have a more comprehensive perspective of this clayey prospects as barrier enhanced layer; aligned to the multilayer barrier system approach for nuclear waste management.

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Author Biography

Gabriel Gonzalo Machado, Entrepreneurship project leader at Argilos

Mining engineer specialized in Clays & Clay minerals

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Published

2021-04-30

How to Cite

Machado, G. G., Krupskaya, V., Zakusin, S. V., HARADA, J., de Souza, R. P., Araujo, L. G., Espinosa, D. C., Montalvan, E. L., Kahn, H., Vicente, R., & Guilhen, S. (2021). Brazilian clays for environmental solutions applied to radioactive waste management. Brazilian Journal of Radiation Sciences, 9(1A). https://doi.org/10.15392/bjrs.v9i1A.1539

Issue

Section

The Meeting on Nuclear Applications (ENAN) 2019

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