Radiological implications of using phosphogypsum as building material: a case study of Brazil
DOI:
https://doi.org/10.15392/bjrs.v8i1.1008Keywords:
Phosphogypsum, NORM, building materials, natural radionuclidesAbstract
Phosphogypsum, a waste byproduct derived from the production of phosphoric acid, is being worldwide stockpiled, posing concerns about the environmental problems originating from this practice. Considerations about the viability of the safe reuse of this material have been raised, among them its potential use as building material. However, as phosphogypsum can contain natural radionuclides in significant concentrations, using it as a building material has radiological implications, which presently prevent such application. In order to evaluate the feasibility of using phosphogypsum in the manufacturing of building elements such as bricks and plates, a comprehensive research was undertaken in Brazil, following a multiple approach. This research included studies related to: Brazilian phosphogypsum characterization; experimental determination of radon exhalation rate; and application of theoretical models to forecast both radon exhalation and external doses in dwellers. In this paper, a comprehensive review of the research carried out in Brazil is presented.
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References
U.S. GEOLOGICAL SURVEY. Mineral commodity sumaries 2017. U.S. Geological Survey, p.202, https://doi.org/10.3133/70180197, 2017.
IAEA - International Atomic Energy Agency. Radiation Protection and Manage-ment of NORM Residues in the Phosphate Industry - Safety Report Series 78, ed. Vienna: International Atomic Energy Agency, 2013.
MACÍAS, F.; PÉREZ-LÓPEZ, R.; CÁNOVAS, C.R.; CARRERO, S.; CRUZ-HERNANDEZ, P. Environmental assessment and management of Phosphogypsum ac-cording to European and United States of America regulations, Procedia Earth Planet Sci, v. 17 p. 666 – 669, 2017.
DNPM - Departamento Nacional de Produção Mineral. Sumário Mineral (2016). Avai-lable at: <http://www.dnpm.gov.br/dnpm/sumarios/sumario-mineral-2015>. Last aces-sed: 8 Dec. 2017.
IBRAM - Information and Analyses on the Brazilian Mineral Economy. IBRAM–7th edition (2012). Available at: http://ibram.org.br/sites/1400/1457/00000380.pdf. Last ac-cessed 8 Dec. 2017.
VALE. Operações e Projetos. Available at; http://www.valefertilizantes.com/valefertilizantes/operacoes.asp. Last acessed: 4 Jan. 2018.
NISTI, M.B. Lixiviation of natural radionuclides and heavy metals in tropical soils amended with phosphogypsum (Doctoral dissertation). Retrieved from the Digital Li-brary of Theses and Dissertations of the University of São Paulo, 2016.
DRAFTTDATA. Novo sistema de bombeamento de fosfogesso. Available at: http://draftdata.com.br/novo-sistema-de-bombeamento-de-fosfogesso. Last accessed 21 Feb. 2018.
RIMA. Relatório de Impacto Ambiental (2014). Available at: http://www.consorciosantaquiteria.com.br/arquivos/RIMA.pdf. Last accessed 21 Feb. 2018.
BORGES R.C., RIBEIRO F.C.A., LAURIA D.C., BERNEDO A.V.B. Radioactive characterization of phosphogypsum from Imbituba, Brazil. J Environ Radioact, v. 126, p. 188-195, 2013.
BORGES, R.C. Caracterização química e radiológica do fosfogesso de Imbituba-SC e aspectos ambientais do uso na recuperação de solos agrícolas (Doctoral dissertation). Retrieved from the Universidade Federal Fluminense, 2011.
BORGES R.C., FERREIRA A.A., DE SOUZA W.F.L., BERNEDO A.V.B. The Geochemistry of Natural Radionuclides in Saline Soils from Brazil Treated with Phos-phogypsum Imbituba. Water Air Soil Pollut, v. 228, p. 59 2017.
MAZZILLI B.P., PALMIRO V., SAUEIA C.H., NISTI M.B. Radiochemical cha-racterization of Brazilian phosphogypsum, J Environ Radioact, v. 49(1), p. 113-122, 2000.
SAUEIA C.H.R., MAZZILLI B.P., FÁVARO D.I.T. Natural radioactivity in phos-phate rock, phosphogypsum and phosphate fertilizers in Brazil, J Radioanal Nucl Chem, v. 264 (2). P. 445-448, 2005.
SAUEIA C.H.R., MAZZILLI B.P., Distribution of Natural Radionuclides in the Production and Use of Phosphate Fertilizers in Brazil, J Environ Radioact, v. 89, p. 229-239, 2006.
SAUEIA C.H.R., MAZZILLI B.P., TADDEI M.H.T. Sequential radioanalytical me-thod for the determination of U and Th isotopes, 226Ra and 210Po using alpha spec-trometry in samples of the Brazilian phosphate industry, J Radioanal Nucl Chem, v. 281, p. 201-204, 2009.
MAZZILLI, B.P.; SAUEIA, C.H.R.; JACOMINO, V.M.F.; MELLO, J.W.V. Natu-ral radionuclides and metals intake into soya, corn and lettuce grown on soil amended with phosphogypsum. Int J Environ Anal Chem, v. 92, p. 1574-1586, 2012.
CNEN - Comissão Nacional de Energia Nuclear. Requisitos de Segurança e Prote-ção Radiológica para Instalações Mínero-Industriais - Norma CNEN NN 4.01, ed. Diário Oficial da União (DOU), Resolução CNEN 208/16, 2016.
CNEN - Comissão Nacional de Energia Nuclear. Nível de isenção para o uso do fosfogesso na agricultura ou na indústria cimenteira - Resolução nº 147, Brasília, 2013.
CNEN - Comissão Nacional de Energia Nuclear – BS Nº 09 de 16/05/2014. Resolu-ção nº 171, Brasília, 2014.
NISTI, M.B., CAMPOS, M.P., MAZZILLI, B.P.,. Natural radionuclides content and radon exhalation rate from Brazilian phosphogypsum piles. J Radioanal Nucl Chem, v. 299, p. 261–264, 2014.
DUEÑAS, C., LIGER, E., CAÑETE, S., PÉREZ, M., BOLÍVAR, J.P., Exhalation of 222Rn from phosphogypsum piles located at the southwest of Spain. J Environ Radioact, v. 95, p. 63-74. 2007.
UNSCEAR - United Nations Scientific Committee on the Effects of Atomic Radia-tion, The 2000 Report to the General Assembly with scientific Annexes. New York: United Nations, 2000.
M.P CAMPOS, L.J.P. COSTA, M.B. NISTI, B.P. MAZZILLI. Phosphogypsum re-cycling in the building materials industry: assessment of the radon exhalation rate. J Environ Radioact, v. 172, p. 232-236, 2017.
NISTI, M.B., CAMPOS, M.P., MAZZILLI, B.P. Natural radioactivity and 222Rn exhalation rate from Brazilian phosphogypsum building materials. In: 7TH INTER-NATIONAL SYMPOSIUM ON NATURALLY OCCURRING RADIOACTIVE MATERIAL, 2013, Beijing. Proccedings of 7th International Symposium on Naturally Occurring Radioactive Material (Supplementary Material). International Atomic Energy Agency, Vienna, 2013. p. 1-6.
FOURNIER, F., GROETZ, J.E., JACOB, F., LETTNER, H., CHAMBAUDET, A., CROLET, J.M. Study of Radon-222 exhalation of phosphogypsum blocks used as bui-lding materials. Comparison with modeling. Radioact Environ, v. 7, p. 582-589, 2005.
MÁDUAR, M.F.; CAMPOS, M.P.; MAZZILLI, B.P.; VILLAVERDE, F.L. Asses-sment of external gamma exposure and radon levels in a dwelling constructed with phosphogypsum plates, J Hazard Mater, v. 190, p. 1063–1067, 2011.
FOLKERTS, K.H., KELLER, G., MUTH, H. An experimental study on diffusion and e exhalation of 222Rn and 220Rn from building materials. Radiat Prot Dosim, v. 9(1), p. 27-34, 1984.
LETTNER, H., STEINHAUSLER, F. Radon exhalation of waste gypsum recycled as building materials. Radiat Prot Dosim, v. 24, p. 415-417, 1988.
SHARMA, N., VIRK, H.S. Exhalation rate study of radon/thoron in some building materials. Radiat Meas, v. 34, p. 467-469, 2001.
KOTRAPPA, P., STIEFF, F. Radon exhalation rates from building materials using electret ion chamber radon monitors in accumulators. Health Phys, V. 97(2), p.163-166, 2009.
SHARAF, M., MANSY, M., SAYED, A.E.L., ABBAS, E. Natural radioactivity and radon exhalation rates in building materials used in Egypt. Radiat Meas, v. 31, p. 491-495, 1999.
DE JONG, P., VAN DIJK, W., VAN DER GRAAF, E.R., DE GROOT, T.J.H. Na-tional survey on the natural radioactivity and 222Rn exhalation rate of building materi-als in The Netherlands. Health Phys, v. 91, p. 200-210, 2006.
RAHAMA, S., MATI, N., MATIULLAH, N., GHAURI, B. Radon exhalation rate from the soil, sand and brick samples collected from NWFP and fata. Pak. Radiat Prot Dosim, v. 124, p. 392-399, 2007.
CHEN, J., RAHMAN, N.M., ATIYA, I.A. Radon exhalation from building materials for decorative use. J Environ Radioact, v. 101, p. 317-322, 2010.
BERETKA, J., MATHEW, P.J. Natural Radioactivity of Australian Building Materi-als, Industrial Wastes and By-products”, Health Phys, v. 48, p. 87–95, 1985.
IAEA - International Atomic Energy Agency. Radiation Protection and Safety of Radiation Sources: International Basic Safety Standards - Safety Standards Series No. GSR Part 3. Ed. Vienna: International Atomic Energy Agency, 2014.
MÁDUAR, M.F.; MAZZILLI, B.P.; NISTI, M.B. Radiation hazard indices in the application of phosphogypsum mixtures as a building material: proposal for a regula-tion. In: ENVIRA 2015 - International Conference Environmental Radioactivity, 2015, Thessaloniki, Greece, 2015.
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