Assessment of natural radioactivity in bottled mineral water from Brazil

Authors

  • Marcelo Bessa Nisti IPEN/CNEN
  • Andressa Nery IPEN/CNEN
  • Cátia H. R. Saueia IPEN/CNEN
  • Fernanda Cavalcante IPEN/CNEN

DOI:

https://doi.org/10.15392/2319-0612.2022.1795

Keywords:

mineral water, natural radionuclides, Liquid Scintillation Counting, gamma spectrometry

Abstract

The approach taken in the WHO Guidelines for controlling radiological hazards in public water supplies has two stages. The first is an initial screening for gross alpha and beta activity to determine whether the activity concentrations are below levels at which no further action is required; and if these screening levels are exceeded, investigation of the concentration of individual radionuclides and comparison with specific guidance levels. Mineral water is obtained directly from natural sources or by extracting groundwater, it is characterized by the quantity of mineral salts, trace elements and other constituents. The bottled water industry is present in the major regions of the world, and the population consumption has increased every year in Brazil and world, also increasing new mineral water mining sites, so it is necessary to constantly check the amount of radioactivity in mineral water. The aim of this study is to quantify the concentration of the natural radionuclides in the bottled mineral water consumed in São Paulo city. The bottled mineral water samples were purchased in a supermarket in São Paulo, with 23 different brands. The determination of gross alpha and beta activity concentration in bottled mineral water by Liquid Scintillation Counting measurement was performed using a 1220 Quantulus™ Ultra Low-Level Liquid Scintillation Spectrometer. The natural radionuclides (226Ra, 228Ra, 210Pb and 40K) were measured by gamma spectrometry, using an HPGe detector. The results obtained in this study can be used for a database on bottled mineral water radioactivity from Brazil.

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References

UNSCEAR. United Nations Scientific Committee on the Effects of Atomic Radiation, The 2000 Report to the General Assembly with scientific Annexes. New York: United Nations, 2000.

UNSCEAR- United Nations Scientific Committee on the Effects of Atomic Radiation “Effects of ionizing radiation”: report to the General Assembly, with scientific annexes. Vol. 1. United Nations Publications. 2008.

M.S. Ministério da Saúde, Nº2914 Portaria do Ministério da Saúde de dezembro de 2011, dispõe sobre os procedimentos de controle e vigilância da qualidade da água para o con-sumo humano e seu padrão de potabilidade, 2011.

WHO. World Health Organization. Guidelines for Drinking-water Quality, fourth edition, Geneva. 2011. ISBN 978 92 4 154815 1.

HESS, C.T.; MICHEL, J.; HORTON, T.R.; PRICHARD, H.M.; CONIGLIO, W.A. The occurrence of radioactivity in public water supplies in the United States. Health Physics, v.. 48(5), p. 553. 1985. DOI: https://doi.org/10.1097/00004032-198505000-00002

PerkinElmer. Liquid Scintillation Analysis-Science and Technology, Editor: Michael J. Kess-ler. 2015.

L´ANNUNZIATA, M. .F. Handbook of Radioactivity Analysis, second edition ed. Elsevier Science. 2003.

ASSIRATI, D. M. ANM – Agência Nacional de Mineração –Departamento Nacional de Produção Mineral – Sumário Mineral, 2018. https://www.google.com/search?q=%C3%81GUA+MINERAL+Doralice+Meloni+Assirati+%E2%80%93+ANM%2FSP&oq=%C3%81GUA+MINERAL+Doralice+Meloni+Assirati+%E2%80%93+ANM%2FSP&aqs=chrome..69i57j33.1877j0j8&sourceid=chrome&ie=UTF-8 Acess: 21 april 2020

GODOY, J. M.; AMARAL, E. C. S.; GODOY, M. L. D. P. Natural radionuclides in Brazilian mineral water and consequent doses to the population. Journal of Envirnomental Radioactivi-ty, v. 53, p. 175-182, 2001. DOI: https://doi.org/10.1016/S0265-931X(00)00123-5

OLIVEIRA, J.; MAZZILLI, B. P.; COSTA P.; TANIGAVA, P. A. Natural radioactivity in Brazilian bottled mineral waters and consequent doses. Journal of Radioanalytical and Nu-clear Chemistry, vol. 249 (1), p. 173–176, 2001. DOI: https://doi.org/10.1023/A:1013221922328

FILHO, C. A. S.; FRANÇA, E. J.; SOUZA, E. M.; RIBEIRO, F. C. A.; SANTOS, T. O.; FARIAS, E. E. G.; ARRUDA, G. N.; NETO, J. A. S.; HONORATO, E. V.; HAZIN, C. A.. Radioactive risk evaluation of mineral water in the Metropolitan Region of Recife, Northeastern Brazil. Journal Radioanalytical Nuclear Chemistry, v. 295, p.1215–1220, 2013. DOI 10.1007/s10967-012-1993-6. DOI: https://doi.org/10.1007/s10967-012-1993-6

NISTI, M.B.; FERREIRA, A. O.; CAMPOS, M. P.; SAUEIA, C. H. R.; MAZZILLI, B. P. Chapter 18. A Comparison of Analytical Methods for Screening Gross Alpha and Beta Radioactivity in Water by Liquid Scintillation Counting and Gas Flow Proportional Counting. Special Publications. 1ed.: Royal Society of Chemistry, p. 148-151, 2015. DOI: https://doi.org/10.1039/9781782622734-00148

ISO 11704 – Water quality - Measurement of gross alpha and beta activity concentration in non-saline water – Liquid scintillation counting method. 2010.

ZAPATA, D. G. Determinació d’índexs d’activitat alfa total i beta total per escintil●lació líquida. PhD thesis, Universitat de Barcelona, 2011.

QUANTULUS. Instrument Manual-Wallac 1220 QuantulusTM Ultra Low Level Liquid Scintillation Spectrometer, PerkinElmer, 2009.

MAESTRO. Software: Maestro for Windows (Emulation software for Gamma Spectroscopy). Model A65-B32 version 5.30, EG&G ORTEC, 2001.

INTERWINNER. InterWinner (WinnerGamma) Spectroscopy Program Family. Version 6.0, EG&G ORTEC, 2004.

NISTI, M.B.; SANTOS, A.J.G.; PECEQUILO, B.R.S.; MÁDUAR, M.F.; ALENCAR, M.M.; MOREIRA, S.R.D. Fast methodology for time counting optimization in gamma-ray spectrometry based on preset minimum detectable amounts. Journal Radioanalytical Nuclear Chemistry, v. 281, p. 283–286, 2009. DOI: https://doi.org/10.1007/s10967-009-0102-y

BROWNE, E. and FIRESTONE, R.B. Table of Radioactive Isotopes. Ed. John Wiley & Sons, Inc. New York, N.Y., 1986.

CURRIE, L.A. Limits for qualitative detection and quantitative determination. Anal. Chem., v. 40, p. 586-593, 1968. DOI: https://doi.org/10.1021/ac60259a007

TAUHATA, L.; VIANNA, M.E.C.; OLIVEIRA, A.E.; FERREIRA, A.C.M.; CONCEIÇÃO, C.C.S. Metrological capability of the Brazilian laboratories of analyses of radionuclides in environmental samples. Applied Radiation and Isotopes, v. 56, p. 409-414, 2002. DOI: https://doi.org/10.1016/S0969-8043(01)00223-8

ICRP. International Commission on Radiological Protection. ICRP PUBLICATION 119. Compendium of Dose Coefficients based on ICRP Publication 60, 2012. https://www.icrp.org/docs/P%20119%20JAICRP%2041(s)%20Compendium%20of%20Dose%20Coefficients%20based%20on%20ICRP%20Publication%2060.pdf. Acess: 10 fev 2020.

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Published

2022-12-04

How to Cite

Nisti, M. B., Nery, A., Saueia, C. H. R. ., & Cavalcante, F. (2022). Assessment of natural radioactivity in bottled mineral water from Brazil. Brazilian Journal of Radiation Sciences, 10(3B (Suppl.). https://doi.org/10.15392/2319-0612.2022.1795

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Section

INAC 2021_XV ENAN

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