Elementary characterization of metals in lipsticks by EDXRF

Catarina Alzira Montenegro Peddis Torres; Sergei Anatolyevich Paschuk; Danielle Cristine Narloch; Janine Nicolosi Corrêa

doi:10.15392/bjrs.v9i1A.1562

Authors

Catarina Alzira Montenegro Peddis Torres Federal University of Technology - Paraná, UTFPR https://orcid.org/0000-0001-5641-5107
Sergei Anatolyevich Paschuk Federal University of Technology - Paraná, UTFPR https://orcid.org/0000-0001-5125-0163
Danielle Cristine Narloch Federal University of Technology - Paraná, UTFPR https://orcid.org/0000-0003-2644-0453
Janine Nicolosi Corrêa ederal University of Technology - Paraná, UTFPR https://orcid.org/0000-0001-9692-7182

DOI:

https://doi.org/10.15392/bjrs.v9i1A.1562

Keywords:

Lipsticks, Heavy metals, EDXRF

Abstract

Usually classified as cosmetic consumer products, makeups usually contain significant quantities of colorants, which may contain toxic and heavy metals, such as Hg, Cd, As, Cr, Tl, and Pb. According the Health Regulatory Agency (ANVISA), lipsticks are classified as low health risk, grade 1. However, similar makeups for the children are classified as grade 2, high risk, and within this category there is no cosmetic product for embellishment. Many metals, present in the colorants, can cross the mucous membranes and skin barrier and could be absorbed into the blood system, which can cause systemic damage to internal organs. Many chemical components present in the lipsticks, such as Al, Pb, Cd, Br, Cu, Zr, Cr, Hg, TiO₂in nanoparticulate form, could be considered as potentially toxic. Present work was undertaken in order to study the presence of mentioned above metals in the samples of commercial lipsticks. The metals characterization and elementary identification was performed using EDXRF technique. This method allows to perform the qualitative and quantitative analysis by means of the characteristic X-rays spectra emitted by the elements present in studied samples. The experimental setup was based on mini X-ray tube with Ag target and detector (AMPTEK). The partial results of the study revealed that the lipstick samples revealed the presence of Mg, Al, Si, P, S, Cl, K, Ca, Ti, Cr, Mn, Fe, Ni, Zn, Br, Rb, which suggest that prolonged and constant use of such cosmetics may constitute a potential threat to the health especially in the case of children.

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References

BRASIL: ANVISA - Brazilian Health Regulatory Agency. Regulation RDC ANVISA 79 de 25 de agosto de 2000 - DOU de 31/08/2000. 6 p. Diário Oficial, República Federativa do Brasil. Po-der Executivo, Brasília, DF, 2000.

KARIN, F. N.; SHAH, A. Do not put makeup on children, say health experts. New Straits Times, 2016.

SIDORYK-WEGRZYNOWICZ, M.; ASCHNER, M. “Manganese toxicity in the central nervous system: the glutamine/glutamate-γ-aminobutyric acid cycle.” Journal of internal medicine, v. 273, p. 466-477, 2013. doi:10.1111/joim.12040

EC - European Parliament and of the Council Regulation no 1223/2009 of 30 november 2009 on cosmetic products. Official Journal of the European Union, 2009. Available at:<https://ec.europa.eu/health/sites/health/files/endocrine_disruptors/docs/cosmetic_1223_2009_ regulation_en.pdf>. Last accessed: 12 Mar. 2020.

U.S. Food and Drug Administration, “Limiting Lead in Lipstick and Other Cosmetics,” De-cember 2016. Available at: <http://www.fda.gov/Cosmetics/ProductsIngredients/Products/ucm137224.htm> Last accessed: 10 Mai. 2020.

U.S. Food and Drug Administration, “FDA’s Testing of Cosmetics for Arsenic, Cadmium, Chromium, Cobalt, Lead, Mercury, and Nickel Content,” December 2016.

Available at: <http://www.fda.gov/Cosmetics/ProductsIngredients/PotentialContaminants/ucm452836.htm> Last accessed: 10 Mai. 2020.

U.S. Food and Drug Administration, “Draft Guidance for Industry: Lead in Cosmetic Lip Products and Externally Applied Cosmetics: Recommended Maximum Level,” December 2016. 8p. Available at: <https://www.fda.gov/media/99866/download>. Last accessed: 10 Apr. 2020.

BRASIL: ANVISA - Brazilian Health Regulatory Agency. Regulation RDC nº 83, de 20 de junho de 2016 (D.O.U. 116). 121p. Diário Oficial, República Federativa do Brasil. Poder Execu-tivo, Brasília, DF. Available at: <http://www.abc-cosmetologia.org.br/wp-content/uploads/2016/06/1RDC_83_2016.pdf> (in Portuguese). Last accessed: 03 Jun. 2020.

EC - European Union. Regulation. N1223/2009 of the European Parliament and of the Council of 30 November 2009 on cosmetic products. Official Journal of the European Union, 2009. 151p. Available at: <https://ec.europa.eu/health/sites/health/files/endocrine_disruptors/docs/cosmetic_1223_2009_regulation_en.pdf>. Last accessed: 03 Apr.2020.

GONDAL, M.A.; SEDDIGI, Z.S.; MOHAMED M. N.; GONDAL, B. Spectroscopic detection of health hazardous contaminants in lipstick using Laser Induced Breakdown Spectroscopy. Journal of Hazardous Materials, v. 175, p. 726 - 732, 2010. Available at: <http://www.ncbi.nlm.nih.gov/pubmed/19926220>. Last accessed: 07 Jun. 2020.

KLAASSEN, C. D., WATKINS III, J. B. Fundamentos em Toxicologia de Casarett e Doull. Lange, AMGH, 2012.

JAN, A.T.; AZAM, M.; SIDDIQUI, K.; ALI, A.; CHOI, I.; HAQ, Q.M. “Heavy Metals and Human Health: Mechanistic Insight into Toxicity and Counter Defense System of Antioxidants.” International journal of molecular sciences, v. 16(12), p. 29592-29630. 10 Dec. 2015, doi:10.3390/ijms161226183

SHI, H.; MAGAYE, R.; CASTRANOVA, V.; ZHAO, J. “Titanium dioxide nanoparticles: a review of current toxicological data. Particle and fiber toxicology, v. 10, p. 2-24, 2013. doi:10.1186/1743-8977-10-15. Available at: <https://particleandfibretoxicology.biomedcentral.com/track/pdf/10.1186/1743-8977-10-15> Last accessed: 07 Mar. 2020.

GAUGLITZ, G.; VO-DINH, T. Handbook of Spectroscopy. Vol.1, p. 363-415. WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim, 2003.

GRIEKEN, R. E. V.; MARCOWICZ, A. A. Handbook of x-ray spectrometry. 2. ed. New York, Marcel Dekker Inc, 2002.