Analysis of the pigments in two modern Egyptian papyri using XRF technique
DOI:
https://doi.org/10.15392/bjrs.v9i1A.1459Keywords:
XRF Technique, Modern papyrus, PigmentsAbstract
In this work, two modern Egyptian papyrus belonging to a private collection were analyzed using X-Ray Fluorescence technique (XRF). The papyri are genuine, made from the papyrus plant, and hand-painted. The papyri were bought in the city of Cairo, Egypt, in the ‘80s and brought to Brazil in the same period. XRF analyses were performed using a portable spectrometer ARTTAX (X-ray tube with Mo anode and a Silicon Drift Detector XFlash®, Bruker AXS Inc.). XRF measurements were carried out under the following experimental conditions: 35 kV, 600 μA, unfiltered x-ray beam, air atmosphere, acquisition time of 600 s. The elements detected in the two papyri were: Si, Al, S, Cl, K, Ca, Ti, Cr, Mn, Fe, Ni, Cu, Zn, Sr, Ba and Pb. Through the XRF analysis it was possible to evaluate the pigments found in the two papyri are different from each other. In the analysis of the blue color, present in the papyrus, it was observed that the composition of this color can be a mixture of two pigments: Egyptian blue (CaCuSi₄O₁₀) and Lithopone (ZnSBaSO4). Most of the pigments on the papyri were thus recognized to be modern, their syntheses, or refinement processes not being known to ancient Egyptians.Downloads
References
ESPINEL A. D., Papyrus, The Encyclopedia of Ancient History, v. 1, p. 5055-5057, 2013.
PAPYRUS MAKING 101: An Introduction to Papyrus - Ancient and Modern. University Library system at the University of Michigan. 2004. Available at: <https://www.lib.umich.edu/papyrus_making/pm_intro.html>. Last accessed:14 Nov. 2018
DI STEFANO L. M., FUCHS R., Characterisation of the pigments in a Ptolemaic Egyptian Book of the Dead papyrus, Archaeol Anthropol Sci, v. 3, p. 229-244, 2011.
GOLER, S., YARDLEY, J. T., CACCIOLA, A., HAGADORN, A., RATZAN, D., BAGNALL, R., Characterizing the age of ancient Egyptian manuscripts through micro-Raman spectroscopy, Journal Raman Spectroscopy, v. 47, p. 1185-1193, 2016.
CALZA, C., ANJOS, M. J., DE SOUZA, S. M. F. M., BRANCAGLION JR., A., LOPES, R. T., X-ray microfluorescence with synchrotron radiation applied in the analysis of pigments from ancient Egypt, Appl. Phys.A, v. 90, p. 75-79, 2008.
BURGIO, L., CLARK, R. J. H., Comparative pigment analysis of six modern Egyptian papyri and an authentic one of the 13th century BC by Raman microscopy and other techniques, J. Raman Spectrosc., v. 31, p. 395-401, 2000.
RIEDERER, J., Recently Identified Egyptian Pigments, Archaeometry, v. 16, p. 102-109, 1974.
KAJIYAA, E. A. M., CAMPOSA, P. H. O.V., RIZZUTTO, M.A, et al., Evaluation of the veracity of one work by the artist Di Cavalcanti through non-destructive techniques: XRF, imaging and brush stroke analysis, Radiation Physics and Chemistry, v. 95, p. 373-377, 2014.
ROSIA, F., BURNSTOCK, A., , VAN DEN BERG, K. J., et al., A non-invasive XRF study supported by multivariate statistical analysis and reflectance FTIR to assess the composition of modern painting materials, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, v. 71, p. 1655-1662, 2009.
ABDRABOU, A., EL HADIDI, N. M. N., HAMED, S., ABDALLAH, M., Multidisciplinary approach for the investigation and analysis of a gilded wooden bed of King Tutankhamun, Journal of Archaeological Science: Reports, v. 21, p. 553-564, 2018.
BENDERITTER, T. Osirisnet – Tomb of Ancient Egypt: Nakht TT52. . Available at: <https://www.osirisnet.net/tombes/nobles/nakht52/e_nakht_01.htm>. Last accessed: 8 Sept. 2018.
SOLÉ, V.A., PAPILLON, E., COTTE, M., WALTER, P., SUSINI, J., A multiplatform code for the analysis of energy-dispersive X-ray fluorescence spectra, Spectrochimica Acta Part B: Atomic Spectroscopy, v. 62, p. 63-68, 2007.
AVL METAL POWDERS. Aluminium pigments. Available at: <https://www.avlmetalpowders.com/en/sector-products/plastic-materials/pigment-range> Last accessed: 6 Apr. 2019
CHEMICAL BOOK. Pigment Red 63:1 Basic information. Available at: <https://www.chemicalbook.com/ProductChemicalPropertiesCB0854904_EN.htm>. Last accessed: 20 June 2019
KOEL COLOURS PRIVATE LIMITED. Difference between Organic Pigments and Inorganic Pigments. Available at: <https://www.koelcolours.com/blog/pigments/difference-organic-pigments-inorganic-pigments/ Last accessed: 15 May. 2018
CHEMICAL BOOK. Organic pigments. Available at: <https://www.chemicalbook.com/ProductCatalog_EN/161211.htm>. Last accessed: 20 June 2019
COLOURLEX. Composition and Properties of Asphalt. Available at: <https://colourlex.com/project/asphalt/>. Last accessed: 14 July 2019.
Downloads
Published
Issue
Section
License
Copyright (c) 2021 Brazilian Journal of Radiation Sciences
This work is licensed under a Creative Commons Attribution 4.0 International License.
Licensing: The BJRS articles are licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/