Assessment of trace elements concentration in cosmetic foundation using X-ray fluorescence technique

Authors

  • Camila Nogueira FEDERAL UNIVERSITY OF TECHNOLOGY – PARANÁ – BRAZIL
  • Rodrigo Zamboni FEDERAL UNIVERSITY OF TECHNOLOGY – PARANÁ – BRAZIL
  • Sergei Paschuk FEDERAL UNIVERSITY OF TECHNOLOGY – PARANÁ – BRAZIL
  • Janine Correa FEDERAL UNIVERSITY OF TECHNOLOGY – PARANÁ – BRAZIL

DOI:

https://doi.org/10.15392/2319-0612.2024.2742

Keywords:

facial foundation, trace elements, heavy metals, X-ray fluorescence

Abstract

Facial foundations play a significant role in beauty routines. However, the presence of heavy metals and toxic elements in cosmetics is a concern due to potential health risks. This study investigated the chemical composition of 52 facial foundation samples obtained in Curitiba and São Paulo, Brazil, using X-ray fluorescence for elemental identification. Quantification was performed using the standard addition method and calibration curves. The results indicated the presence of Cu, Zn, Br, Zr, and Ba in concentrations exceeding the limits established by the Brazilian Health Regulatory Agency (ANVISA). Cd and Ni, elements prohibited in cosmetic formulations, exhibited maximum concentrations of 277 ± 51 µg/g and 130 ± 10 µg/g, respectively. The highest concentration of Zr reached 589 ± 57 µg/g, approximately six times the regulatory limit. In contrast, Ba concentrations exceeded 14,000 µg/g, approximately 60 times the limit, with the highest concentration recorded at 30,867 ± 1,500 µg/g. These findings underscore the need for rigorous monitoring of cosmetic products in Brazil and highlight discrepancies between the marketed cosmetics and ANVISA regulations. Additionally, this study contributes to the growing knowledge regarding potentially harmful elements in facial foundations.

Downloads

Download data is not yet available.

References

[1] ELDRIDGE, L. Face Paint: The Story of Makeup. New York: Abrams Image, 2015.

[2] GUICHARD, S.; ROULIER, V. Facial Foundation. In: DRAELOS, Z. (Ed.). Cosmetic Dermatology: Products and Procedures. 2 ed. Durham, North Carolina: John Wiley & Sons, Ltd, 2016. cap. 20, p. 177-185. DOI: https://doi.org/10.1002/9781118655566.ch20

[3] BRASIL. Ministério da Saúde. Agência Nacional de Vigilância Sanitária (ANVISA). RDC No 752, de 19 de setembro de 2022 dispõe sobre a definição, a classificação, os requisitos técnicos para rotulagem e embalagem, os parâmetros para controle microbiológico, bem como os requisitos técnicos e procedimentos para a regularização de produtos de higiene pessoal, cosméticos e perfumes, 2022. Available at < https://www.in.gov.br/en/web/dou/-/resolucao-rdc-n-752-de-19-de-setembro-de-2022-430784222>

[4] THE EUROPEAN PARLIAMENT AND OF THE COUNCIL. Regulation (EC) No 1223/2009 of 30 November 2009 on cosmetic products. European Union, 2009. Available at < https://health.ec.europa.eu/system/files/2016-11/cosmetic_1223_2009_regulation_en_0.pdf>

[5] LIM et al. Non-cancer, cancer, and dermal sensitization risk assessment of heavy metals in cosmetics. Journal of toxicology and environmental health. Part A, v. 81, n. 11, p. 432–452, 2018. DOI: https://doi.org/10.1080/15287394.2018.1451191

[6] LODYGA-CHRUSCINSKA, E.; SYKULA, A. Hidden Metals in Several Brands of Lipstick and Face Powder Present on Polish Market. Cosmetics, v. 5, 2018. DOI: https://doi.org/10.3390/cosmetics5040057

[7] ARSHAD, H.; MEHMOOD, M. Z.; SHAH, M. H.; ABBASI, A. M. Evaluation of heavy metals in cosmetic products and their health risk assessment. Saudi Pharmaceutical Journal, v. 28, n. 7, p. 779–790, 2020. DOI: https://doi.org/10.1016/j.jsps.2020.05.006

[8] SHOMAR, B.; RASHKEEV, S. N. A comprehensive risk assessment of toxic elements in international brands of face foundation powders. Environmental research, v. 192, p. 110274, jan. 2021. DOI: https://doi.org/10.1016/j.envres.2020.110274

[9] BOROWSKA, S.; BRZÓSKA, M. M. Metals in cosmetics: implications for human health. Journal of applied toxicology : JAT, v. 35, n. 6, p. 551–572, jun. 2015. DOI: https://doi.org/10.1002/jat.3129

[10] CHEN et al. Skin damage induced by zinc oxide nanoparticles combined with UVB is mediated by activating cell pyroptosis via the NLRP3 inflammasome–autophagy– exosomal pathway. Particle and fibre toxicology, v. 19, p. 1-22, 2022. DOI: https://doi.org/10.1186/s12989-021-00443-w

[11] BERTIN, E. P. Principles and Practice of X-Ray Spectrometric Analysis. New York: Springer, 1975. 1080 p. DOI: https://doi.org/10.1007/978-1-4613-4416-2

[12] HARRIS, D. C. Quantitative Chemical Analysis. 7. ed. New York: W.H. Freeman, 2007. 828 p.

[13] SOLÉ, V. A.; PAPILLON, E.; COTTE, M.; WALTER, P.; SUSINI, J. A multiplatform code for the analysis of energy-dispersive X-ray fluorescence spectra. Spectrochimica Acta Part B: Atomic Spectroscopy, v. 62, n. 1, p. 63–68, 2007. DOI: https://doi.org/10.1016/j.sab.2006.12.002

[14] BRASIL. Ministério da Saúde. Agência Nacional de Vigilância Sanitária (ANVISA). RDC No 529, de 4 de Agosto de 2021 dispõe sobre a lista de substâncias que não podem ser utilizadas em produtos de higiene pessoal, cosméticos e perfumes, 2021. Available at < https://www.in.gov.br/en/web/dou/-/resolucao-de-diretoria-colegiada-rdc-n-529-de-4-de-agosto-de-2021-337524962>

[15] BRASIL. Ministério da Saúde. Agência Nacional de Vigilância Sanitária (ANVISA). RDC No 628, de 10 de março de 2022 dispõe sobre a lista de substâncias corantes permitidas para produtos de higiene pessoal, cosméticos e perfumes, 2022. Available at < https://www.in.gov.br/en/web/dou/-/resolucao-rdc-n-628-de-10-de-marco-de-2022-386108199>

[16] BRASIL. Ministério da Saúde. Agência Nacional de Vigilância Sanitária (ANVISA). RDC No 600, de 9 de fevereiro de 2022 dispõe sobre a lista de filtros ultravioletas permitidos para produtos de higiene pessoal, cosméticos e perfumes, 2022. Available at < https://portal.in.gov.br/en/web/dou/-/resolucao-rdc-n-600-de-9-de-fevereiro-de-2022-380633694>

[17] SAAH, S. A.; BOADI, N. O.; SAKYI, P. O.; DARKO, G.; MENSAH, M. B. Risk of Exposure to Trace Elements through the Application of Facial Makeup Powders. Journal of Chemistry, v. 2022, 2022. DOI: https://doi.org/10.1155/2022/9229134

[18] ABDEL-GHANY, H. A.; RAGAB, F. Studies of radioactive contaminations and heavy metal contents in cosmetics. International Journal of Low Radiation, v. 10, n. 3, p. 181-197, 2016. DOI: https://doi.org/10.1504/IJLR.2016.081451

Downloads

Published

2025-05-12

How to Cite

Assessment of trace elements concentration in cosmetic foundation using X-ray fluorescence technique. Brazilian Journal of Radiation Sciences, Rio de Janeiro, Brazil, v. 12, n. 4A (Suppl.), p. e2742, 2025. DOI: 10.15392/2319-0612.2024.2742. Disponível em: https://bjrs.org.br/revista/index.php/REVISTA/article/view/2742. Acesso em: 14 may. 2025.