Determination of 93Zr in radioactive waste from nuclear power plants using Inductively Coupled Plasma Mass Spectrometry

Authors

  • Thiago César Oliveira Universidade Federal de Minas Gerais - UFMG
  • Roberto Pellacani Guedes Monteiro Centro de Desenvolvimento da Tecnologia Nuclear - CDTN
  • Aluísio Souza Reis Júnior Centro de Desenvolvimento da Tecnologia Nuclear - CDTN
  • Geraldo Frederico Kastner Centro de Desenvolvimento da Tecnologia Nuclear - CDTN
  • Arno Heeren Oliveira Universidade Federal de Minas Gerais - UFMG

DOI:

https://doi.org/10.15392/bjrs.v6i1.317

Keywords:

Zirconium, Evaporator Concentrate waste, TRU, ICPMS

Abstract

The zirconium isotope 93Zr is a long-lived pure β-particle-emitting radionuclide produced from 235U fission and from neutron activation of the stable isotope 92Zr and thus occurring as one of the radionuclides found in nuclear reactors. Due to its long half-life, 93Zr is one of the radionuclides of interest for the performance of assessment studies of waste storage or disposal. This paper describes the determination of 93Zr in evaporator concentrate (EC) sample from nuclear power plant (PWR). A zirconium selective separation using liquid-liquid extraction and TRU column were used before the ICPMS measurement to remove isobaric interferences.20-21 93Nb detection limit of 0.045 μg L-1 was obtained for 93Zr determination by ICPMS technique.

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Author Biographies

  • Thiago César Oliveira, Universidade Federal de Minas Gerais - UFMG
    Departamento de Engenharia Nuclear - DENU
  • Roberto Pellacani Guedes Monteiro, Centro de Desenvolvimento da Tecnologia Nuclear - CDTN
    SERTA - Radioquímica
  • Aluísio Souza Reis Júnior, Centro de Desenvolvimento da Tecnologia Nuclear - CDTN
    Serta - Radioquímica
  • Geraldo Frederico Kastner, Centro de Desenvolvimento da Tecnologia Nuclear - CDTN
    Serta Radioquímica
  • Arno Heeren Oliveira, Universidade Federal de Minas Gerais - UFMG
    Departamento de Energia Nuclear - DENU

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Published

2018-01-28

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How to Cite

Determination of 93Zr in radioactive waste from nuclear power plants using Inductively Coupled Plasma Mass Spectrometry. Brazilian Journal of Radiation Sciences, Rio de Janeiro, Brazil, v. 6, n. 1, 2018. DOI: 10.15392/bjrs.v6i1.317. Disponível em: https://bjrs.org.br/revista/index.php/REVISTA/article/view/317.. Acesso em: 5 nov. 2024.

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