Influence of pyrolytic temperature on uranium adsorption capability by biochar derived from macauba coconut residue
DOI:
https://doi.org/10.15392/bjrs.v7i2A.590Keywords:
biochar, macauba, uranium, adsorption, pyrolysisAbstract
Biochar (BC) is a carbon-rich product obtained when biomass is thermally decomposed at relatively low temperatures (under 700ºC) and limited supply of oxygen in a process called pyrolysis. Because of its porous structure, charged surface and surface functional groups, BC exhibits a great potential as an adsorbent. Its characteristics strongly depend on the feedstock and the pyrolysis conditions, in which the temperature is the key parameter. The aim of this study was to evaluate the adsorption potential for the removal of uranium, U(VI), from aqueous solutions using BC obtained through the pyrolysis of the macauba coconut endocarp as a function of the final pyrolytic temperature. The influence of parameters such as pH, sorbent dose and initial concentration on the adsorption of U(VI) was investigated. The maximum adsorption capacity (q) was achieved for the BC obtained at 250°C (BC250), which presented a removal percentage of approx. 86%, demonstrating the potential of the BC from macauba endocarp for treatment of wastewaters.
Downloads
References
NEA/OECD - Nuclear Energy Agency Organization for Economic Co-Operation and Develop-ment, Environmental Activities in Uranium Mining and Milling, Paris: OECD, 1999, 177p.
SAKR, K.; SAYED, M.S; HAFEZ, M. B. Immobilization of radioactive waste in mixture of ce-ment, clay and polymer. J Radioanal Nucl Chem, v. 256, n. 2, p. 179-184, 2003.
OZDEMIR, T.; USANMAZ, A. Use of poly(methyl methacrylate) in radioactive waste manage-ment: I, radiation stability and degradation. Prog Nucl Energy, v. 51, n. 2, p. 240-245, 2009.
IAEA – International Atomic Energy Agency, Combined methods for liquid radioactive waste treatment, IAEA-TECDOC-1336, Vienna: IAEA, 2003, 250p.
DE GISI, S.; LOFRANO, G.; GRASSI, M.; NOTARNICOLA, M. Characteristics and adsorp-tion capacities of low-cost sorbents for wastewater treatment: A review. Sustainable Materials and Technologies, v. 9, p. 10-40, 2016.
INYANG; M. I.; GAO, B; YAO, Y.; XUE, Y; ZIMMERMAN, A.; MOSA, A; PUL-LAMMANAPPALLIL, P.; OK, Y. S.; CAO, X.A review of biochar as a low-cost adsorbent for aqueous heavy metal removal. Critical Reviews in Environmental Science and Technology, v. 46, n. 4, 2016.
PATRA, J. M.; PANDA, S. S.; DHAL, N. K. Biochar as a low-cost adsorbent for heavy metal removal: A review. Internat J of Res in Biosci, v. 6, n. 1, p. 1-7, 2017.
LEHMANN, S. J. Biochar for Environmental Management, 1st ed. Oxford: Earthscan, 2009.
BRIDGWATER, A. V.; PEACOCKE, G. V. C. Fast pyrolysis processes for biomass. Renewa-ble Sustainable Energy Reviews, v. 4, p. 1-73, 2000.
LU, Q.; LI, W-Z.; ZHU, X-F. Overview of fuel properties of biomass fast pyrolysis oils. Energy Conversion and Management, v. 50, p. 1376-1383, 2009.
ANTAL, M. J. J.; GRONLI, M. The art, science, and technology of charcoal production. Indus-trial and Engineering Chemistry Research, v. 42, p. 1619-1640, 2003.
LUA, A. C.; YANG, T.; GUO, J. Effects of pyrolysis conditions on the properties of activated carbons prepared from pistachio-nut shells. Journal of Analytical and Applied Pyrolysis, v. 72, p. 279-287, 2004.
ÖZÇIMEN, D.; ERSOY-MERIÇBOYU, A. A study on the carbonisation of grapeseed and chestnut shell. Fuel Processing Technology, v. 89, p. 1041-1046, 2008.
RIOS, R. D. F.; FONSECA, R. M.; CREN, E. C.; ANDRADE, M. H. C. Adsorção de fenol no carvão ativado produzido a partir do endocarpo do fruto da macaúba. In: XX Congresso Brasileiro de Engenharia Química, 2014, Florianópolis. Annals... Florianópolis: COBEQ 2014.
GUILHEN, S. N.; MASEK, O.; ORTIZ, N.; FUNGARO, D. A. Pyrolytic temperature evalua-tion of macauba biochar for uranium adsorption from aqueous solutions. In: Biochar: Production, Characterization and Applications Conference, 2017, Alba, Annals… Alba: ECI Conference, 2017.
YI, Z.; YAO, J.; ZHU, M.; CHEN, H; WANG, F.; YUAN, Z.; LIU, X. Batch study of uranium biosorption by Elodea Canadensis biomass. Journal of Radioanal Nucl Chem, v. 310, p. 505-513, 2016.
ROYER, B.; CARDOSO, N. F.; LIMA, E. C.; RUIZ, V. S. O.; MACEDO, T. R.; AIROLDI, C. Organofunctionalized kenyaite for dye removal from aqueous solution. Journal of Colloid and Interface Science, v. 336, p. 398-405, 2009.
ŐZACAR, M.; SENGIL, I. A.Adsorption of metal complex dyes from aqueous solutions by pine sawdust. Bioresource Technology, v. 96, p. 791-795, 2005.
SHUKLA, A.; ZHANG, Y. H.; DUBEY, P.; MARGRAVE, J. L.; SHUKLA, S. S. The role of sawdust in the removal of unwanted materials from water. J Hazard Mat, v. 95, p. 137-152, 2002.
Downloads
Published
Issue
Section
License
Copyright (c) 2021 Brazilian Journal of Radiation Sciences
This work is licensed under a Creative Commons Attribution 4.0 International License.
Licensing: The BJRS articles are licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/