Evaluation of polybutadiene rubbers using FTIR spectra
DOI:
https://doi.org/10.15392/bjrs.v5i2.198Keywords:
radiation, dosimetry, detectorsAbstract
Radiation dosimetry for medical and industrial purposes has increasingly evolved over the last few decades with the introduction of various new detectors. Depending on the properties exhibited for radiation dosimetry, some detectors present their applications in a specific area. From a physics point of view, an ideal dosimeter should be able to measure absorbed dose. In this work, synthetic materials based on polybutadiene rubbers (PBR) were proposed as a new class of radiation detectors. The influence of radiation dose on their properties has been investigated for application in radiation dosimetry. The rubber samples were exposed to absorbed doses from 10 Gy up to 250 Gy, using a 60Co Gamma Cell-220 system. Their responses were carried out with a Fourier Transform Infrared (FTIR) Spectrometer to investigate the presence of absorbance peaks. The results suggested the existence of a relationship between the absorbed doses and the absorbance peaks associated with stretching (1300-1200 cm-1), deformation (1450-1340 cm-1) and vibration (1500-1400 cm-1) processes in the material.
- Views: 335
- PDF Downloads: 434
Downloads
References
CHMIELEWSKI, A.G.; HAJI-SAEID, M.; AHMED, S.. Progress in radiation processing of polymers. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, v. 236, n. 1, p. 44-54, 2005.
MCKEEN, L.W. “Plastics used in medical devices," in Handbook of polymer applications in medicine and medical devices. Elsevier US, Philadelphia, 2014.
MANSHAIE, R.; KHORASANI, S.N.; VESHARE, S.J.; ABADCHI, M.R. Effect of electron beam irradiation on the properties of natural rubber (nr)/styrene butadiene rubber (sbr) blend. Radiation Physics and Chemistry, v. 80, n. 1, p. 100-106, 2011.
ABADCHI, M.R.; JALALI-ARANI, A. The use of gamma irradiation in preparation of polybutadiene rubber nanopowder; its effect on particle size, morphology and crosslink structure of the powder. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, v.320, n.1, p.1-5, 2014.
ABIONA, A.A.; OSINKOLU, A.G. Gamma-irradiation induced property modification of polypropylene. International Journal of Physical Sciences, v. 5, n.7, p.960-967, 2010.
INTERNATIONAL ATOMIC ENERGY AGENCY (IAEA). Dosimetry for Radiation Pro-cessing. Viena, Austria. 2000.
OLIVEIRA, L.M.; ARAUJO, P.L.B.; ARAUJO, E.S. The effect of gamma radiation on mechanical properties of biodegradable polymers poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate). Materials Research, v. 16, n.1, p. 195-203, 2013.
ZHANG, Y.; ZHAO, S.F.; LI, Y.T.; XIE, L.D.; SHENG, K.L. Radiation effect on styrene-butadiene-styrene copolymer. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, v. 266, n.1, p. 3431 3436, 2008.
LAL, J.; MARK, J.E. Advances in Elastomers and Rubber Elasticity. Springer US, New York. 1986.
PROKOF'EVA, N.I.; SHVARTSBERG, G.I.; SPERANTOVA, I.B. Calculation of the infra-red spectrum of 1,4-trans-polybutadiene. Journal of Applied Spectroscopy, v. 27, n.3, p. 1185-1188, 1977.
Published
How to Cite
Issue
Section
License
Licensing: The BJRS articles are licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/